Simultaneous spectrophotometric determination of calcium and magnesium with Arsenazo III

  • 66 Pages
  • 0.10 MB
  • 8436 Downloads
  • English
by
Calcium -- Spectra., Magnesium -- Spectra., Spectrophotom
Statementby Howard Price Shafer II.
The Physical Object
Pagination[10], 66 leaves, bound :
ID Numbers
Open LibraryOL14258496M

Simultaneous spectrophotometric determination of calcium and magnesium with chlorphosphonazo-III by flow injection analysis. Analytica Chimica Acta, DOI: /S(00) J. Cacho Palomar, A.

L pez Molinero, M. Iba toutes-locations.com by: A dual -pH simultaneous direct spectrophotometric method for the determination of calcium and magnesium using Arsenazo III has been developed.

An absorption spectra study was made of Arsenazo III and its magnesium, calcium, strontium, and barium complexes at various pH values.

Description Simultaneous spectrophotometric determination of calcium and magnesium with Arsenazo III PDF

This study showed that total calcium Author: Howard Price Shafer. A method for the simultaneous spectrophotometric determination of calcium and magnesium based on the formation of their complexes with 4-(2-pyridylazo)resorcinol is proposed. The absorbance band yielded by the mixture was resolved by applying a computer multilinear regression program to the corrected, standardized spectrum of each metal ion as toutes-locations.com by: For the simultaneous determination, the detection limits for both calcium and magnesium were mg 1- 1 (SIN= 2); relative standard deviations (n= 12) were % for mg I` calcium and % for mg I` toutes-locations.com by: Sep 01,  · A new analytical method using Back-Propagation (BP) artificial neural networks and spectrophotometry for simultaneous determination of calcium and magnesium in tap water, the Yellow River water and seawater is established.

By condition experiment, the optimum analytical conditions for calcium, magnesium and Arsenazo (III) color reactions are obtained. Levenberg Cited by: 6. In this paper, an FIA method for the simultaneous spectrophotometric determination of calcium and magnesium, in mineral waters, with arsenazo(III) at pH is chemometrically studied from the point of view of the model used for the calibration and from the point of view of the toutes-locations.com by: 9.

Jul 22,  · Abstract. A new analytical method using Back-Propagation (BP) artificial neural networks and spectrophotometry for simultaneous determination of calcium and magnesium in tap water, the Yellow River water and seawater is established.

By condition experiment, the optimum analytical conditions for calcium, magnesium and Arsenazo (III) Cited by: 6. A method for the simultaneous flow injection spectrophotometric determination of calcium and magnesium with Arsenazo III based on the use of diode-array detector and.

A method for the simultaneous flow injection spectrophotometric determination of calcium and magnesium with Arsenazo III based on the use of diode-array detector and merging zones is described. The method is applicable to the resolution of mixtures in which the chromogenic reagent has a high absorbance and its spectrum strongly overlaps those of its toutes-locations.com by: Abstract.

Graduation date: A dual -pH simultaneous direct spectrophotometric method for\ud the determination of calcium and Simultaneous spectrophotometric determination of calcium and magnesium with Arsenazo III book using Arsenazo III has\ud been developed.\ud An absorption spectra study was made of Arsenazo III and its\ud magnesium, calcium, strontium, and barium complexes at various\ud pH values.

A new analytical method using Back-Propagation (BP) artificial neural networks and spectrophotometry for simultaneous determination of calcium and magnesium in tap water, the Yellow River water and seawater is established.

By condition experiment, the optimum analytical conditions for calcium, magnesium and Arsenazo (III) color reactions are toutes-locations.com by: 6. Magnesium does not significantly interfere in calcium determination using Arsenazo III. In this method the absorbance of the Ca-Arsenazo III complex is measured bichromatically at / nm.

The resulting increase in absorbance of the reaction mixture is directly proportional to the calcium concentration in the sample.

A method for the simultaneous spectrophotometric determination of calcium and magnesium in mineral waters with an FIA system is tested. The method is based on the reaction between the analytes. Spectrophotometric Determination of Magnesium, Calcium, Strontium and Barium Present in Pairs by Use of Tetramethylmurexide R.

KOHN Institute of Chemistry, Slovak Academy of Sciences, Bratislava 9 Received June 30, A spectre-photometric method is described for the determination of. A new method for the simultaneous determination of calcium and magnesium by flow injection analysis (FIA) using a photometric diode array (PDA) detector.

In this paper, in the presence of polyvinylalcohol a new method for the spectrophotometric determination of magnesium has been established using arsenazo-III.

Download Simultaneous spectrophotometric determination of calcium and magnesium with Arsenazo III EPUB

Appropriate amount of polyvinyl alcohol can make sensitivity of the determination of magnesium increase %. Polyvinylalcohol has a sensitizing toutes-locations.com: Yan-Ru Tang. Simultaneous determination of uranium and thorium using arsenazo III as a chromogenic reagent at pH by H-point standard addition method (HPSAM) and partial least squares (PLS) calibration is.

At millimolar dye concentrations, typical of physiological calcium transient determinations in situ, a second complex involving two arsenazo III molecules and one calcium ion is additionally formed.

A third complex, involving one arsenazo III molecule and one calcium ion Cited by: A rapid and sensitive spectrophotometric procedure for determining calcium and magnesium with Chlorophosphonazo III is described. Either calcium or magnesium may be determined at pH in the.

With the Arsenazo III reagent we clearly improved the within-lab and between-lab imprecision of the calcium determination. The accuracy of the Arsenazo III method was established with a reference method (atomic absorption spectrophotometry) and good results were obtained with Cited by: spectrophotometric determination of calcium and magnesium in blood serum with Arsenazo I, o- (1,8- dihydroxy -3, 6- disulfo naphthylazo)- benzenearsonic acid, and EGTA, r ethylenebis (oxyethylenenitrilo)] tetraacetic acid.

The absorbance due to the complexation of both calcium and magnesium by Arsenazo I is determined at mµ and pH 9. Preparation of Arsenazo and Calcium Chloride Solutions 1. (a) Using the FW of Arsenazo III ( g/mole for the disodium salt) calculate the amount in grams needed to prepare mL of a x M aqueous Arsenazo III solution.

Enter your calculation in your lab. Use of multivariate curve resolution for determination of chromium in tanning samples using sequential injection analysis Increasing the scope and power of. is not suited for routine use.4 Spectrophotometric methods using either o-cresolphthalein complexone (CPC) or arsenazo III metallochromic indicators are most commonly used.5,6,7 Arsenazo III has a high affinity for calcium and is not temperature dependent as is CPC.

Calcium in the patient sample binds with arsenazo III to form a calcium-dye. Summary. A new procedure has been developed for the sequential spectrophotometric determination of water-soluble calcium and magnesium in soils using CPA-I.

Optimum conditions for the spectrophotometric determination, Beer's law range, sensitivity of the color reaction, precision and the interference of various foreign ions are toutes-locations.com by: 3. separation and pre-concentration of trace amounts of cerium(iii) on octadecyl silica membrane discs modified with 1,3,5-trithiacyclohexane and its spectrophotometric determination by arsenazo(iii) Mojtaba Shamsipur, Mohammad Yousefi, Zahra Ghasemi, Leila Hagiagha-Babaei, Cited by: A single, stable reagent and automatable methods utilizing the reagent for the assay of calcium in serum and aqueous samples, such as urine.

(Aqueous samples contain little or no protein.) The reagent includes arsenazo III, 8-hydroxyquinoline, a buffer that does not bind calcium competitively with arsenazo III and that provides a reagent pH from about to about 10, the buffer being in Cited by: magnesium precipitates as Mg(OH) 2.

So, for simultaneous determination of Mg and Ca one needs two titrations: one at pH=10 and using Eriochrome Black T (the sum of moles of both metals is obtained) and second, at pH=12 and using Murexide (only calcium is titrated). Important: the change of.

Details Simultaneous spectrophotometric determination of calcium and magnesium with Arsenazo III PDF

Jul 01,  · Fergusons et al. 13 has reported that the CPZ-III spectrophotometric procedure can be used to determine additively calcium and magnesium concentrations in the same sample.

However, it seems that it is impossible to use CPZ-III in a liquid form because it non-specifically reacts with albumin in samples under acidic to neutral toutes-locations.com by: 2.

determination of a few elements, we’ll also investigate some of these practical concerns during the experiment.

An obvious (if somewhat simplistic) application of the determination of calcium and magnesium in water is testing for hard water. Water hardness is defined as the total concentration of alkaline earth metal ions in water.

ABSTRACT A single, stable reagent and automatable methods utilizing the reagent for the assay of calcium in serum and aqueous samples, such as urine. (Aqueous samples contain little or no protein.) The reagent includes arsenazo III, 8-hydroxyquinoline, a buffer that does not bind calcium competitively with arsenazo III and that provides a reagent pH from about 8.

5 to about 10, the buffer.Determination of Total Calcium and Magnesium Ion Concentration. Method Sample Preparation For samples that are already in solution, such as freshwater, seawater and milk, no further preparation is needed. For solid samples such as eggshells and limestone.Catalytically enhanced spectrophotometric determination of manganese in seawater by flow-injection analysis with a commercially available resin for on-line preconcentration; Direct determination of iron in acidified (pH ) seawater samples by flow injection analysis with catalytic spectrophotometric detection: Application and intercomparison.